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Williams will play Olympia Houston, a generous benefactor at the Hamptons Heritage Center for Rare and Orphan Diseases.

She has a reputation for dating powerful men — or is it Olympia who makes her suitors powerful?

Read more ' Royal Pains' Admits ' Jane the Virgin, Blacklist' Actresses (Exclusive) Season six of the medical drama ended with Hank Med, or at least team members Evan (Paulo Costanzo), Divya (Reshma Shetty) and Jeremiah (Ben Shenkman) joining the board of directors of Hamptons Heritage Hospital.

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She has conquered the musical charts, Broadway, music videos, television and motion pictures.

She has sold millions of albums worldwide and she has achieved critical acclaim as an actress on stage, in film and on television.

Williams was born in Millwood, New York, to Helen L.

The hottest photos of Vanessa Williams, the American singer and actress.

The gorgeous actress, who absolutely has a spot in the list of sexiest women over 40, was also a beauty queen when younger and released several albums that earned her Grammy and Tony nominations.

The versatile entertainer also appeared with the unmistakably sexy cast of "Ugly Betty" and recorded the Oscar-winning song "Colors of the Wind" from Disney's These Vanessa Williams pics were taken from a variety of different sources, including photoshoots for promotional purposes and magazine, and have been turned into a curated image gallery containing only the cutest pictures and jpgs from around the Web.

While there are many sexy Vanessa Williams pictures, collecting photos together of one of entertainment's hottest women, these are the hottest around.

Williams joins in a recurring role, playing General Rockwell, the tough, brilliant head of the top secret, black ops secret government agency, known as D.

The third season of TNT’s fan-favorite series will see the Librarians confronting a new antagonist, which has shown up in the form of D.

Investigating “Statistical Anomalies,” Williams’ character sets her sights on apprehending the Librarians and obtaining the magical artifacts contained in the Library. Williams’ role in “The Librarians” is not the first time she’s played a villainous boss, as she starred as Wilhelmina Slater in “Ugly Betty.” Her latest television roles have been an arc on “The Good Wife” and a guest episode of “Broad City.” She also starred on “Desperate Housewives” and “666 Park Avenue.” Up next, she will topline VH1’s scripted drama “Satan’s Sisters,” which is inspired by a dramatic daytime talk show like “The View.” “The Librarians” Season 3 premieres this fall on TNT, though no premiere date has been set.

— The Department of Statistical Anomalies — whose mission is to apprehend the Librarians and take control of the Library and all the magical artifacts hidden inside.